'Holy Grail' of molecular electronics - Single molecule diode performs 50x better than past designs

05/25/2015 - 00:00

Under the direction of Latha Venkataraman, associate professor of applied physics at Columbia Engineering, researchers have designed a new technique to create a single-molecule diode, and, in doing so, they have developed molecular diodes that perform 50 times better than all prior designs. Venkataraman's group is the first to develop a single-molecule diode that may have real-world technological applications for nanoscale devices. Their paper, "Single-Molecule Diodes with High On-Off Ratios through Environmental Control," is published May 25 in Nature Nanotechnology.

"Our new approach created a single-molecule diode that has a high (>250) rectification and a high "on" current (~ 0.1 micro Amps)," says Venkataraman. "Constructing a device where the active elements are only a single molecule has long been a tantalizing dream in nanoscience. This goal, which has been the 'holy grail' of molecular electronics ever since its inception with Aviram and Ratner's 1974 seminal paper, represents the ultimate in functional miniaturization that can be achieved for an electronic device."


Ref:  Single-molecule diodes with high rectification ratios through environmental control. Nature Nanotechnology (2015) |  DOI: 10.1038/nnano.2015.97 (Error DOI not found)